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Why is the emphasis on the thermal stability of lead salt stabilizers in the production of PVC sheets (especially rigid PVC sheets) a response to their core function and specific processing challenges?
2025-12-26
When PVC resin is heated to processing temperatures (typically 160-200°C), the molecular chains begin to break, releasing hydrogen chloride (HCl) gas. HCl has an autocatalytic effect, accelerating further chain breakage and forming polyene structures with conjugated double bonds. This causes the material's color to change from white to yellow, red, and brown, eventually turning black and carbonized, resulting in a complete loss of physical properties.


Therefore, the first priority in any PVC processing is to inhibit thermal decomposition, and the core mission of stabilizers is precisely "thermal stability."


Compared to pipes and profiles, the extrusion process of PVC sheets presents a more severe challenge to thermal stability due to: longer material residence time, meaning the PVC melt endures high-temperature thermal stress for a longer period, dramatically increasing the risk of decomposition.


A higher risk of localized overheating; if the formulation or process is inappropriate, these "hot spots" can become the starting points for decomposition, spreading rapidly and forming persistent "yellow lines" or "black spots" on the sheet. Strict requirements for color and appearance, coupled with insufficient thermal stability, are the primary causes of initial yellowing. Any premature coloring (initial yellowing) renders the product unusable.


Furthermore, to reduce costs, a certain proportion of recycled scrap material is often added during board production. Recycled material has already undergone one heat treatment, partially depleting its thermal stability system, resulting in even worse thermal stability.


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